Scientific American Supplement No. 447

Produced by Don Kretz, Juliet Sutherland, and Distributed Proofreaders SCIENTIFIC AMERICAN SUPPLEMENT NO. 447 NEW YORK, JULY 26, 1884 Scientific American Supplement. Vol. XVIII, No. 447. Scientific American established 1845 Scientific American Supplement, $5 a year. Scientific American and Supplement, $7 a year. * * * * * TABLE OF CONTENTS. I. CHEMISTRY.–The Bitter Substance
This page contains affiliate links. As Amazon Associates we earn from qualifying purchases.
Writer:
Language:
Published:
  • 26/6/1884
Edition:
Buy it on Amazon FREE Audible 30 days

Produced by Don Kretz, Juliet Sutherland, and Distributed Proofreaders

[Illustration]

SCIENTIFIC AMERICAN SUPPLEMENT NO. 447

NEW YORK, JULY 26, 1884

Scientific American Supplement. Vol. XVIII, No. 447.

Scientific American established 1845

Scientific American Supplement, $5 a year.

Scientific American and Supplement, $7 a year.

* * * * *

TABLE OF CONTENTS.

I. CHEMISTRY.–The Bitter Substance of Hops.–By Dr. H. BUNGENER. –What gives hops their bitter taste?–Processes for obtaining hop-bitter acid.–Analysis of the same.

II. ENGINEERING AND MECHANICS.–Improvements in the Harbor of Antwerp.–With engraving of caisson for deepening the river.

Progress of Antwerp.–Recent works in the harbor.

Bicycles and Tricycles.–By C.V. BOYS.—Advantages of the different machines.–Manner of finding the steepness of a hill and representing same on a map.–Experiments on ball bearings.– The Otto bicycle.

The Canal Iron Works, London.

Marinoni’s Rotary Printing Press.–With 2 engravings.

Chenot’s Economic Filter Press.–With engraving.

Steel Chains without Welding.–Method and machines for making same.–Several figures.

III. TECHNOLOGY.–Some Economic Processes connected with the Cloth Making Industry.–By Dr. WM. RAMSAY.–How to save and utilize soap used in wool scouring.–To recover the indigo from the refuse.–Extraction of potash from _suint_.–Use of bisulphide of carbon.

IV. PHYSICS. ELECTRICITY, ETC.–Thury’s Dynamo Electric Machine. –5 figures.

Breguet’s Telephone.

Munro’s Telephonic Experiments.–9 figures.

Apparatus for Maneuvering Bichromate of Potassa Piles from a Distance.–2 figures.

Magnetic Rotations.–By E.L. VOICE.–1 figure.

Lighton’s Immersion Illuminator.–1 figure.

Foucault’s Pendulum Experiments.–By RICHARD A. PROCTOR. –4 figures.

V. ARCHITECTURE, ART, ETC.–St. Paul’s Vicarage, Forest Hill, Kent.–2 engravings.

Designs for Iron Gates.–An engraving.

VI. ASTRONOMY.–A New Lunarian.–By Prof. C.W. MACCORD. –With 3 figures.

VII. GEOLOGY.–Coal and its Uses.–By JAMES PYKE.–Formation of carboniferous rocks and the coal in the same.–Processes of nature.–Greatness of this country due to coal.–Manufacture of gas.–Products of the same.

VIII. NATURAL HISTORY, BOTANY. ETC.–The Wine Fly.–The egg.–Larva.–Pupa and fly.

The “Potetometer.” an Instrument for Measuring the Transpiration of Water by Plants.–1 figure.

Bolivian Cinchona Forests.

Ferns.–Nephrolepis Davillioides Furcans and Nephrolepis Duffi. –2 engravings.

IX. PHYSIOLOGY, HYGIENE, ETC.–The Upright Attitude of Mankind. –Review of a lecture by Dr. S.V. CLEVENGER, in which he tries to prove that man must have originated from a four footed being.

Our Enemies, the Microbes.–Affections caused by the same.– Experiments of Davaine, Pasteur, and others.–How to prevent bacterides from entering the body.–5 figures.

X. BIOGRAPHY.–Gaston Plante, the Scientist.–With portrait

Warren Colburn, the American Mathematician.

* * * * *

IMPROVEMENTS IN THE HARBOR OF ANTWERP.

The harbor of Antwerp, which, excepting those of London and Liverpool, is the largest in Europe, has been improved wonderfully during the last decade. Before 1870 it was inferior to the harbor at Havre, but now it far surpasses the same. The river Scheldt, which is about 1,500 ft. wide, was badgered out up to the vertical walls of the basin, so that the largest ships can land at the docks. The river was deepened by the use of caissons, in the lower parts of which the workmen operated in compressed air. The annexed cut shows that part of one of the caissons which projects above the surface of the water. The depth of the river at low tide is about 26 ft., and at high tide about 39 ft. Some of the old sluices, channels, basins, etc., which were rendered useless by the improvements made in the river Scheldt have been filled up, and thereby the city has been enriched by several handsome and elegant squares.–_Illustrirte Zeitung_.

* * * * *

PROGRESS OF ANTWERP.

Antwerp is now the chief port on the Continent. Since 1873 the progress has continued, and made very rapid advances. In 1883 the tonnage of the port reached 3,734,428 registered tons. This marvelous development is partly due to the position of Antwerp as the embarking point from the Continent of Europe to America, and partly also to the recent additions and changes which have been carried out there, and which, now nearly completed, have made this cosmopolitan port one of the best organized in the world. This is so well known that vessels bound for Switzerland with a cargo of corn from Russia pass Marseilles and go two thousand miles out of their way for the purpose of unloading at Antwerp. No other port, in fact, offers the same facilities. There is not another place in the world where fifty vessels of 3,000 tons can come alongside as easily as the penny boats on the Thames run into the landing.

[Illustration: CAISSONS FOR DEEPENING THE RIVER AT ANTWERP.]

Since the opening of the St. Gothard Tunnel nearly all the alimentary provisions that Italy sends to the British Isles pass through Antwerp. In 1882 82,000,000 eggs and 30,000 pounds of fruit were shipped there for England. The greater part of these came from Italy. Antwerp has become also an important port for emigrants; 35,125 embarked in 1882, out of which number 3,055 were bound for New York. The city was always destined, from its topographical position, to be at the head of a very considerable traffic; political reasons alone for many years prevented this being the case. These have happily now disappeared, and, since 1863, when the “Scheldt was liberated,” the progress of commerce has been more rapid than even the most ardent Antwerp patriot dared hope. At that date the toll of 1s. 11d. on all vessels going up the river, and of 71/2d. on vessels going down, was abolished, and reforms were introduced among the taxes on the general navigation; the tax on tonnage in the port itself was abolished, and the pilot tax was lowered. The results of these measures became immediately apparent. Traffic increased with such rapidity that in 1876 the crowding on the quays was such that the relation of the tonnage to the length of the quay was about 270 tons per yard, which is four times as great as at Liverpool.

A few words now, briefly, as to the nature of the important works[1] completed at Antwerp. They were commenced in 1877, and have opened for the port an era of prosperity such as was never experienced even during the sixteenth century, the zenith of her splendor. These works have cost L4,000,000, and have necessitated the employment of 12,000 tons of wrought iron, of 490,000 cubic yards of brickwork and concrete, of 32,000 cubic yards of masonry, and of more than 3,300,000 cubic yards of earthwork in filling and dredging, etc. The quay walls run the whole length of the town, a distance of rather more than two miles. It rests on a foundation laid without timber footings, and giving a depth of twenty-six feet at low water, sufficient drawing for the largest ships afloat. Beyond this wall are the real quays, which consists of first a line of rails reserved for hydraulic cranes serving to unload vessels and deposit their cargo railway trucks; secondly, a second line of rails parallel with the first, on which these trucks are stationed; thirdly, sheds extending toward the town for a width of one hundred and fifty feet, and covered with galvanized iron sheetings. A third line of rails parallel with the two others runs from end to end of these sheds, and a number of lines placed transversely with this one connect it by means of spring bridges with, fourthly, four more lines also parallel with the quays, whence the goods start for the different stations, and thence to their destinations. The total width of these immense constructions is about three hundred and twenty feet. Such is their magnitude that about six hundred houses had to be pulled down to make place for them. A railing running along their entire length cuts them off from the town.

[Transcribers note 1: changed from ‘words’]

During the course of last year 4,379 vessels entered the port of Antwerp, gauging a total of 3,734,428 tons, which places Antwerp, as I have already stated, at the head of European ports. In 1882 the tonnage of Havre was only 2,200,000, that of Genoa 2,250,000, and of Bilboa 315,000, owing to its iron ore exports. Among the English ports a few only exceed Antwerp. London is still the first port in the world, with a tonnage of 10,421,000 tons, and Liverpool the second, with 7,351,000 tons; Newcastle follows with 6,000,000 tons, also in excess of Antwerp, but both Hull and Glasgow are below, with respectively 1,875,000 and 2,110,000 tons.–_Pall Mall Gazette_.

* * * * *

BICYCLES AND TRICYCLES.

[Footnote: A recent lecture before the Society of Arts, London.]

By C.V. BOYS.

The subject of this paper is one of such wide interest, and of such great importance, that it is quite unnecessary for me to make any apology for bringing it to your notice. Exactly two months ago, I had the honor of dealing with the same subject at the Royal Institution. On that occasion I considered main principles only, and avoided anything in which none but riders were likely to take an interest, or which was in any way a matter of dispute. As it may be assumed that the audience here consists largely of riders, and of those who are following those matters of detail, the elaboration, simplification, and perfection of which have brought the art of constructing cycles to its present state of perfection, I purpose treating the subject from a totally different point of view. I do not intend, in general, to describe anything, assuming that the audience is familiar with the construction of the leading types of machines, but rather to consider the pros and cons of the various methods by which manufacturers have striven to attain perfection. As a discussion on the subject of this paper will doubtless follow–and I hope makers or riders of every class of machine will freely express their opinion, for by so doing they will lend an interest which I alone could not hope to awaken–I shall not consider it necessary to assume an absolutely neutral position, which might be expected of me if there were no discussion, but shall explain my own views without reserve.

The great variety of cycles may be grouped under the following heads:

1. The Bicycle unmodified.
2. The Safety bicycle, a modification of 1. 3. The Center-cycle.
4. The Tricycle, which includes five general types: (a.) Rear steerer of any sort.
(b.) Coventry rotary.
(c.) Front steerer of any sort (except e). (d.) Humber pattern.
(e.) The Oarsman.
5. Double machines: sociables and tandems. 6. The Otto.

It is perfectly obvious that not one machine is superior to all others in every respect, for if that were the case, the rest would rapidly become extinct. Not one shows any signs of becoming extinct, and, therefore, it may be assumed that each one possesses some points in which it is superior to others, the value of which is considered by its riders to far outweigh any points in which it may be inferior. The widely varying conditions under which, and purposes for which, machines are used and the very different degrees of importance which differently constituted minds attach to the peculiarities of various machines, will, probably, prevent any from becoming extinct. Nevertheless, the very great advantages which some of these possess over others will, no doubt, in time become evident by the preponderance of the better class of machines.

The bicycle, which surpasses all other machines in simplicity, lightness, and speed, will probably, for these reasons, always remain a favorite with a large class. The fact that it requires only one track places it at a great advantage with respect to other machines, for it is common for a road which is unpleasant from mud or stones to have a hard, smooth edge, a kind of path, where the bicyclist can travel in peace, but which is of little advantage to other machines. Again, the bicycle can be wheeled through narrow gates or door ways, and so kept in places which are inaccessible to tricycles. One peculiarity of the bicycle, and to a certain extent of the center-cycle, is that the plane of the machine always lies in the direction of the resultant force, that the machine leans over to an amount depending on the velocity and the sharpness of the curve described. For this reason all lateral strain on the parts is abolished, and if we except the slipping away of the wheel from under the rider, which can hardly occur on a country road, an upset from taking a curve too quickly is impossible. This leaning to either side by the machine and rider gives rise to that delightful gliding which none but the bicyclist or the skater can experience. In this respect the bicycle has an enormous advantage over any machine, tricycle or Otto, which must at all times remain upright, and which must, therefore, at a high speed, be taken round a curve with discretion.

The perfect and instantaneous steering of the bicycle, combined with its narrowness, counteract, to a great extent, the advantage which the tricyclist has of being able to stop so much more quickly, for the bicyclist can “dodge” past a thing for which the rider of the three-wheeler must pull up. In one other respect the bicyclist has an advantage which, though of no real importance, has great weight with many people. The bicycle well ridden presents a picture of such perfect elegance that no one on anything else need expect to appear to advantage in comparison.

The chief disadvantage of the bicycle is the fact that a rider cannot stop for any purpose, or go back a little, without dismounting. For town riding, where a stoppage is frequently necessitated by the traffic, this perpetual mounting and dismounting is not only tiresome, but wearying, so much so that few bicyclists care to ride daily in town.

The position of the rider on a bicycle, with respect to the treadles, is by no means good, for if he is placed sufficiently far forward to be able to employ his weight to advantage without bending himself double, he will be in so critical a position that a mere touch will send him over the handles. He has, therefore, to balance stability and safety against comfort and power; the more forward he is, the more furiously he can drive his machine, and the less does he suffer from friction and the shaking of the little wheel; the more backward he is, the less is he likely to come to grief riding down hill, or over unseen stones. The bicyclist is no better off than the rider of any other machine with a little wheel, the vibration from which may weary him nearly as much as the work he does. The little wheel as a mud-throwing machine engine is still more effective on the bicycle than it is on any tricycle, for in general it is run at a higher speed.

I now come to the usual complaint about the bicycle. There is a fashion just now to call it dangerous and the tricycle safe. But the difference in safety has been much exaggerated. The bicyclist is more likely to suffer from striking a stone than his friend on three wheels, but then he should not strike one where the tricyclist would strike a dozen. Properly ridden, neither class of machine can be considered dangerous; an accident should never happen except it be due to the action of others. People, carts, cattle, and dogs on the road are liable to such unexpected movements, that the real danger of the cyclist comes from the outside; to danger from absolute collapse, due to a hidden flaw in the materials employed, every one is liable, but, the bicyclist more remotely than the tricyclist, owing to the greater simplicity of his machine. The bicyclist, though he has further to fall in case of an accident from any of these causes, is in a better position than the tricyclist, for he is outside instead of inside his machine; he can in an instant get clear.

It would appear that many tricyclists consider accidents of the kind next to impossible, for in several machines the rider is so involved that an instantaneous dismount without a moment’s notice, at any speed, is absolutely impossible. There remains one objection, which, however, should be of next to no importance–the difficulty of learning the bicycle prevents many from taking to the light and fast machine, because they are afraid of a little preliminary trouble.

The chief objections to the bicycle, then, are the liability of the rider to go over the handles, the impossibility of stopping very quickly, and the inability to remain at rest or go backward, and the difficulty of learning.

The first two of these are, to a large extent, overcome in the safety bicycles, but not without the introduction of what is in comparison a certain degree of complication, or without the loss of the whole of the grace or elegance of the bicycle. On almost all of these safety bicycles the rider is better placed than on the unmodified bicycle, but though safer, I do not think bicyclists find them complete in speed, though, no doubt, they are superior in that respect to the tricycle. Though they do not allow the rider to stop without dismounting, the fatigue resulting from this cause is less than it is with a bicycle, owing to the fact that with the small machines the rider has so small a distance to climb. Of these machines, the Extraordinary leaves the rider high up in the air on a full-sized wheel, but places him further back and more over the pedals. The motion of these is peculiar, being not circular, but oval, a form which has certain advantages.

In the Sun and Planet and Kangaroo bicycles a small wheel is “geared up,” that is, is made to turn faster than the pedals, so as to avoid the very rapid pedaling which is necessary to obtain an ordinary amount of speed out of a small wheel. In each of these the pedals move in a circular path, and their appearance is in consequence less peculiar than that of the Facile, which, in this respect, does not compare favorably with any good machine. The pedal motion on the Facile is merely reciprocating. Riders of machines where circular motion is employed, among them myself, do not believe that this reciprocating motion can be so good as circular, but I understand that this view is not held by those who are used to it. Of course, the harmonic motion of the Facile pedal is superior to the equable reciprocating motion employed in some machines where speed is an object, especially with small wheels.

If I have overlooked anything typical in the modified bicycle class, I hope some one will afterward supply the omission, and point out any peculiarities or advantages.

That very peculiar machine, the center-cycle, seems to combine many of the advantages of the bicycle and tricycle. On it the rider can remain at rest, or can move backward; he can travel at any speed round curves without an upset being possible; he can ride over brickbats, or obstructions, not only without being upset, but, if going slowly, without even touching them. As this machine is very little known, a few words of explanation may be interesting.

In the first place, the rider is placed over the main wheel, as in the bicycle, but much further forward. There are around him, on or near the ground, four little wheels, two before and two behind, supported in a manner the ingenuity of which calls for the utmost admiration. Turning the steering handle not only causes the front and rear pairs to turn opposite ways, but owing to their swiveling about an inward pointing axis, the machine is compelled to lean over toward the inside of the curve; not only is this the case, but each pair rises and falls with every inequality of the road, if the rider chooses that they run on the ground; but he can, if he pleases, arrange that in general they ride in the air, any one touching at such times as are necessary to keep him on the top of the one wheel, on which alone he is practically riding. He can, if he likes, at any time lift the main wheel off the ground and run along on the others only. The very few machines of the kind which I have seen have been provided with foot straps, to enable the rider to pull as well as push, which is a great advantage when climbing a hill, but this is on every machine except the Otto, of which I shall speak later, considered a dangerous practice.

Some of the objections to the bicycle to which I have referred were sufficient to prevent many, especially elderly men, from dreaming of becoming cyclists. So long as the tricycle was a crude and clumsy machine, there was no chance of cycling becoming a part, as it almost is and certainly soon will be, of our national life. The tricycle has been brought to such a state of perfection that it is difficult to imagine where further progress can be made.

Perhaps it will be well to mention what is necessary in order that a three-wheeled machine may be made to roll freely in a straight line, and also round curves. At all times each wheel must be able to travel in its own plane in spite of the united action of the other two. To run straight, the axes of all the wheels must obviously be parallel. To run round a curve, the axis of each must, if continued, pass through the center of curvature of the curve. If two wheels have a common axis, the intersection of the two lines forming the axes can only meet in one point. To steer such a combination, therefore, the plane of the third wheel only need be turned. If the axis of no two are common, then the planes of two of the wheels must be turned in order that the three axes may meet in a point.

Not only does free rolling depend on the suitable direction of the planes of the wheels, each wheel must be able to run at a speed proportional to its distance from the point of intersection of the three axes, i.e., from the ever-shifting center of curvature.

The most obvious way, then, of contriving a three wheeler is to drive one wheel, steer with another, and leave the third, which must be opposite the driver, idle. The next in simplicity is to drive with one wheel, and steer with the other two, having one in front and the other behind. So far then, the single driving rear-steerer and the Coventry rotary pattern are easily understood. The evils of single driving, minimized, it is true, to a large extent, in the Coventry rotary, have led to the contrivance of means by which a wheel on each side may be driven without interfering with their differential motion in turning a corner.

Three methods are commonly used, but as only two are employed on tricycles, I shall leave the third till I come to the special machine for which it is necessary. The most easy to understand is the clutch, a model of which I have on the table. If each main wheel is driven by means of one of these, though compelled to go forward by the crankshaft, it is yet free to go faster without restraint. By this means “double driving” is effected in several forms of tricycle.

Differential gear, which is well understood, and of which there are several mechanically equivalent forms, divides the applied driving power, whether forward or backward, between the main wheels, equally if the gear is perfect, unequally if imperfect. To understand the effect of the two systems of driving, and of single driving, let us place on grooves a block which offers resistance to a moving force. If we wish to move it, and apply our force at the end of one side, it will tend to turn round as well as move forward, and much friction will be spent on the guides by their keeping it straight.

This is the single driver. If, instead of applying force at one side, we push the block bodily forward by a beam moving parallel to itself, then so long as the guides are straight no strain will be put upon them, even though one side of the block is resisted more than the other; if, however, the guides compelled the block to travel round a curve, then the power, instead of being divided between the two sides in such proportion as is necessary to relieve the guides of all strain, is suddenly applied only to the inside, and the effect is that of a single driver only. This is the clutch. Lastly, if the last-mentioned beam, instead of being pushed along parallel to itself, were pivoted in the middle, and that pivot only pushed, the same power would be applied to each side of the block, and no strain would be thrown on the guides, whether straight or curved, so long as the resistance opposed to the block on the two sides were equal; if, however, one side met with more resistance than the other, then the guides would have to keep the block straight. This is the differential gear.

I have assumed that in the last case the force was applied to the middle of the beam; this corresponds to every evenly-balanced gear. In the gear employed by Singer, which is not evenly balanced, but which derives its good qualities from its simplicity, the same effect is produced as if the beam were pivoted on one side of the center instead of on the center. Thus, though both sides are driven, one is driven more than the other. On the whole, there is no doubt that the balanced gear gives a superior action to the clutch, for except when the two sides of the machine meet with very different resistance, and then only when running straight, the clutch will not compare with the other. The clutch also gives rise to what is considered by most riders a grave defect, the inability to back treadle, while the free pedal, which is an immediate consequence, is considered by others a luxury.

On the other hand, this same free pedal can be obtained on differentially driven machines to which speed and power gear have been applied.

Of the relative merits of different forms of differential gear there is little to be said. Perhaps it will not be thought I am unduly thrusting myself forward, if I refer to a scheme of my own, in which no toothed wheels are employed, but in which two conical surfaces are driven by a series of balls lying in the groove between them, and jambed against them by a recessed ring.

I have here a large wooden diagrammatic model, and a small working model in steel, which shows that the new principle employed is correct, namely, that a ball while jambed is free to turn, or if turning is able to jamb. All Humbers, and most front steerers, employ differential gearing; in some front steerers the clutch of necessity is used.

Neglecting for the present the different modes of transmitting power from the pedals to the main wheels, it is possible now to consider the four typical builds of tricycle. The only advantage that a rider can find in a rear-steerer is the open front, so that in case of accident he can more easily clear himself of his machine; as I have already remarked, this power of instantly escaping seems to be considered by many as of no importance.

In a rear-steerer which has not an open front, whether driven by a clutch or by differential gear, I fail to discover any good quality. The steering of a rear-steerer is so very uncertain, that such machines cannot safely be driven at anything like a high speed, because any wheel meeting with an obstruction will, by checking the machine, diminish the weight on the steering wheel just at the time when a greater weight than usual should be applied. It is for the corresponding reason that the steering of a front-steerer is so excellent; the more the machine is checked by obstruction, by back treading, or by the brake, the greater is the weight on the front wheel.

For shooting hills, or for pulling up suddenly, no machine of any kind will compare with a good front-steerer. In all respects it is superior to the rear-steerer if we except the open front, but against this may be set the fact that on many the rider can mount from behind, or can dismount in the same manner while the machine is in motion. Experience shows that the front-steerer is for general excellence, safety, easy management, and light-running, the best all-round tricycle that is to be had.

The Humber build, which departs less from the ordinary bicycle than any othar, is far superior to all others for speed; it is, however, somewhat difficult to manage, for the steering is not only delicate, but critical, requiring constant care lest a stone or other obstruction should take the rider unawares, and steer the machine for him.

The control which a skillful rider of the Humber has over his machine is wonderful; the elegance of the machine among tricycles is unequaled. So great a favorite is this form, especially among the better class of riders, that almost every firm have brought out their own Humber, each with a distinguishing name.

The only improvement or change, whichever it may be, that has been made by others with which I am acquainted, is the triple steering, in which the hind wheel moves the opposite way to the others. The corresponding change in the bicycle was soon discarded; I do not know what advantage can result from the increased delicacy of steering here. I should have thought it delicate enough already.

One noticeable change in the front-steering tricycle, which has been largely made, lately, is the substitution of central for side gearing, in consequence of which bicycle cranks can be employed, instead of the cranked axle, with its fixed throw. This gives an appearance of lightness which the older types of machine do not possess.

I now come to that very difficult and all-important subject, the method of transmitting power from the body of the rider to the main axle. Next to the structural arrangement, this is most important in distinguishing one type of machine from another.

The first to which I shall refer is the direct action employed on the National and the Monarch tricycles. It is obvious that by having no separate crank shaft, much greater simplicity and cheapness and less friction are attained than can be possible when the extra bearings and gear generally used are employed. In this respect the direct action machines undoubtedly have an advantage, but an advantage of any kind may be too dearly bought, as it certainly is here.

In the first place, the direct action can only be applied to a rear-steering, clutch-driven machine, or single driver, for if the wheels were not free to run ahead, it would be impossible to go round a curve. In the second place, the rider must be placed at such a height for his feet to work on the axle that the machine, of necessity, is very unstable, and is likely to upset if ridden without great caution round a curve. Thirdly, to diminish as far as possible this last objection, miserable little wheels must be employed, which cannot be geared up, that is, made to travel faster than the treadles, and so be equivalent to larger wheels. Therefore, though it is likely that at such low speeds only as it is safe to run such a machine it may move more easily than a machine of a recognized type, and though direct action would undoubtedly be advantageous if it did not entail defects of a most serious order of magnitude, we may dismiss this at once from our consideration. It is true that in the Monarch a few inches of height are gained by the hanging pedals, but I question very much whether one machine is much better than the other.

The chain which is used on almost every make of machine cannot be considered perfect; it is, on the whole, a dirty and noisy contrivance, giving rise to friction where the links take and leave the teeth of the pulleys; stretching, or rather lengthening, by wear, and, finally, allowing back lash, which is most unpleasant. In spite of all this, it affords a convenient and reliable means of transmitting power, which is applicable to every type of tricycle, except one.

Instead of a chain, an intermediate or idle wheel has been tried, but this has not been found advantageous. The intermediate wheel has been removed, and the crank and wheel pulley allowed to gear directly together, making reverse motion of the feet necessary, and possibly reducing friction.

The crank and connecting rod are employed in some machines. If there are two only, they must not be placed in opposite positions, but be fixed at an angle, so that there are times when each rod is under compression, a strain which delicate rods cannot stand. In the three-throw crank, employed in the Matchless tricycle, this objection is obviated, for one, at least, is at all times in such a position as to be in tension. The objection to the crank is the fact that it weakens the shaft, and that it can only be used with a clutch, not with a differential gear.

The most silent, neatest, and cleanest driver, the one of which the working friction is least, is the endless steel band, so well known in connection with the Otto bicycle. This is not, as far as I am aware, employed on any tricycle, makers probably fearing lest it should slip. The Otto shows that it can safely be employed.

I have devised a scheme, of which I now show a model, which seems to me to be free from the objections which may be urged against other methods; but I, of course, cannot be considered in this respect a judge. Eccentrics are well known as equivalent to cranks, but if used in the same way, with a connecting rod, either fatal friction or enormous ball-bearings would be necessary. Instead of these, I connect two pair of equal eccentrics by an endless band embracing each, so that the band acts like a connecting rod without friction, and, at the same time, acts by its turning power as on the Otto, thus making two eccentrics sufficient instead of three, and carrying them over the dead points.

There is one more system of transmitting power employed on a few machines. In these, a band or line passes over the circumference of a sector or wheel, and the power is directly applied to it. The motion of the feet in the omnicycle, and of the hands and body in the Oarsman, is therefore uniform. There would be no harm in this if it were not for the starting and the stopping, which cannot be gradual and at the same time effective in machines of this type. For this reason, a high speed cannot be obtained; nevertheless, these machines are better able to climb hills than are tricycles with the usual rotary motion, for, at all parts of the stroke–which may be of any length that the rider chooses–his driving power on the wheels is equal. The ingenious expanding drums on the omnicycle make this machine exceptionally good in this respect, for increased leverage is effected without increased friction, which is the result of “putting on the power” in some of the two-speed contrivances.

Having spoken of the Oarsman tricycle, I must express regret that I have not been able to find an opportunity to ride on or with the machine, so that I cannot from observation form an opinion of its going qualities. There can be no doubt that the enormous amount of work that can be got from the body in each stroke on a sliding seat in a boat must, applied in the same manner on the Oarsman tricycle, make it shoot away in a surprising manner; whether such motion, when continued for hours, is more tiring than the ordinary leg motion only, I cannot say for certain, but I should imagine that it would be. The method by which the steering is effected by the feet, and can with one foot be locked to a rigidly straight course, is especially to be admired.

There is much difference of opinion with respect to the most suitable size for the wheels of machines. Except with certain machines, this has nothing to do with the speed at which the machine will travel at a given rate of pedaling, for the wheels may be geared up or down to any extent, that is made to turn more quickly or slowly than the cranks. Thus the most suitable speeding is a separate question, and must be treated by itself.

Large wheels are far superior to small wheels in allowing comfortable, easy motion, a matter of considerable importance in a long journey. They are also far better than small for running over loose or muddy ground, for with a given weight upon them they sink in less, from the longer bearing they present, and this, combined with their less curvature, makes the everlasting ascent which the mud presents to them far less than with a smaller wheel. On the other hand, the large wheel is heavier, and suffers more from air resistance than the small wheel. For racing purposes a little wheel, geared up of course, is certainly better than a high wheel; for comfortable traveling, and in general, the high wheel is preferable. Though this is certainly the case, it does not follow that large wheels are worth having on a machine when there is already one little wheel. If the rider is to be worried with the evils of a little wheel at all, it is possible that any advantage which large wheels would give him would be swamped by the vibration and mud-sticking properties of the small steering wheel. One firm, in their endeavors to minimize these evils, have designed machines without any very small wheels; all three wheels are large, and a steadier and more comfortable motion no doubt results.

High and low gearing are the natural sequel to high and low wheels. Of course the lower the gearing the greater is the mechanical advantage in favor of the rider when meeting with much resistance, whether from wind, mud, or steepness of slope. In spite of this, for some reason which I cannot divine, the machines with excessively low gear do not seem to obtain so great an advantage in climbing hills as might be expected. To make such a machine travel at a moderate speed only, excessively rapid pedaling is necessary, and the rider is made tired more by the motion of his legs than by any work he is doing. The slow, steady stroke by which a rider propels a high-geared machine is far more graceful and less wearying than the furious motion which is necessary on a low-geared machine. The height up to which the driving-wheels are usually geared may be taken as an indication of the ease with which any class of machines runs. A rider on a low-geared machine can start his machine much more quickly than an equal man on one that has high gearing, and therefore in a race he has an advantage at first, which he speedily loses as his rapid pedaling begins to tell. For ordinary riding the slight loss of time at starting is a matter of no importance whatever.

There are several devices which enable us to obtain the advantages of high and low gearing on the same machine, which at the same time give the rider the benefit of a free pedal whenever he wishes. On some single driving rear-steering tricycles the connection on one side is for speed, and that on the other for power, either being in action at the wish of the rider, or both speed and power combinations are applied on the same side. To drive with a power gear a single wheel only seems to me to be the height of folly; in my opinion no arrangement of this type is worthy of serious attention. Among the better class of machines there are three methods by which this change is effected–first, that employed on the omnicycle, to which I have already referred; secondly, an epicyclic combination of wheelwork which moves as one piece when set for speed, thus adding nothing to the working friction except by its weight, but which works internally when set for power, thus reducing to a small extent, by the additional friction, the gain of power which the rider desires; thirdly, a double set of chains and pulleys, each set always in movement, so that, whether set for speed or power, there is rather more friction than there would be if there were no additional chains, but these are free from that increased friction due to toothed wheel gearing, from which the epicyclic contrivances suffer only when set for power. There is much difference of opinion whether any of these arrangements are worth carrying, for perhaps nine miles, for the sake of any advantage that may be obtained in the tenth. It is on this account that the drums on the omnicycle are so excellent; whether expanded or not, there is, on their account, no loss of work whatever, for there is no additional friction. The subject of these two speed gears will, I hope, be discussed; it is one which, though not new, is coming more to the front, and about which much may be said.

Having now dealt with the means by which tricycles are made to climb hills more easily, I wish to leave the subject of bicycles and tricycles altogether for a few minutes, to say a few words which may specially interest those who are fond of trying their power in riding up our best known hills. The difficulty of getting up depends to a large extent on the surface and on the wind, but chiefly on the steepness. The vague manner in which one hill is compared with another, and the wild ideas that many hold who have not made any measurements, induces me to describe a method which I have found specially applicable for the measurement of steepness of any hill on which a cyclist may find himself, and also a scheme for the complete representation of the steepness and elevation of every part of a hill on a map so as to be taken in at a glance. The force required to move the thing up a slope is directly proportional not to the angle, but to the trigonometrical sine of that angle. To measure this, place the tricycle, or Otto–a bicycle will not stand square to the road, and therefore cannot be used–pointing in direction at right angles to the slope of the hill, so that it will not tend to move. Clip on the top of the wheel a level, and mark that part of the road which is in the line of sight. Take a string made up of pieces alternately black and white, each exactly as long as the wheel is high, and stretch it between the mark and the top of the wheel. If there are n pieces of string included, the slope is 1 in n, for by similar triangles the diameter of the wheel is to the length of the string as the vertical rise is to the distance on the road. This gives the average steepness of a piece sufficiently long to be worth testing, because an incline only a few feet in length, of almost any steepness, can be mounted by the aid of momentum.

There is only one process, with which I am acquainted, which supplies a method of representing on a map the steepness of a road at every part. Contours, of course, show how far one has to go to rise 50 or 100 feet, but as to whether the ascent is made uniformly or in an irregular manner, with steep and level places, they tell us nothing. Let the course of a road be indicated by a single line where it is level, and by a pair of lines where inclined. Let the distance between the lines be everywhere proportional to the steepness, then the greatest width will show the steepest part, and an intermediate width will show places of intermediate steepness; the crossing of the lines, which must be distinguishable from one another, will show where the direction of the slope changes. Further, the size of the figure bounded by the two lines will show the total rise; a great height being reached only by great steepness or by great length, a large figure being formed only by great width or by great length. Those who are mathematically inclined will recognize here that I have differentiated the curve representing the slope of the bill, and laid the differential curve down in plan.

Having wandered off my subject, I must return to more mechanical things, and give the results of some experiments which I have made on the balls of ball bearings. There is no necessity to argue the case of ball vs. plain bearings, the balls have so clearly won their case, that it would be waste of time to show why. Of the wear of the twelve balls forming one set belonging to the bearings of the wheels of my Otto, I have on a previous occasion spoken; I may, however, repeat that in running 1,000 miles, the twelve balls lost in weight only 1/20.8 grain, or each ball lost only 1/250 grain. The wear of the surface amounted to only 1/158000 inch; at the same rate of wear, the loss in traveling from here to the moon would amount to only 1/34.3 of their weight. I examined each ball every 200 miles, and was surprised to find that on the whole the wear of each, during each journey, varied very little. The balls experimented on were a new set obtained from Mr. Bown. I also had from him one ball of each of each of the following sizes 3, 4, 5, 6, and 7 16ths of an inch in diameter, as I was curious to know what weight they would suppport without crushing. As as preliminary experiment, I placed a spare 5/16 ball between the crushing faces of the new testing machine at South Kensington, and applied a gradually increasing force up to 7 tons 91/2 cwt., at which it showed no signs of distress. On removing it I found that it had buried itself over an angle of about 60 deg. in the hard steel faces, faces so hard that a file would not touch them. Those marks will be a permanent record of the stuff of which the ball was made. The ball itself is sealed in a tube, so that any one who is curious to see it can do so. Finding that the crushing faces were not sufficiently hard, I made two anvils of the best tool steel, and very carefully hardened them. These, though they were impressed slightly, were sufficiently good for the purpose. In the following table are the results of the crushing experiments:

3/16 ball at 2 tons 13 cwt. did not break, but crushed on removing part of the weight.

1/4 ball at 3 tons 15 cwt. did not break, but crushed on removing part of the weight.

5/16 ball at 4 tons 9 cwt. broke.

3/8 ball at 8 tons 6 cwt. did not break, crushed under another 120 lb.

7/16 ball crushed before 3 tons, with which I was starting, had been applied. Examination showed that the steel bar of which it was made had been laminated.

These experiments do not tell much of importance; they are curious, and perhaps of sufficient interest to bring before your notice. The fragments are all preserved in tubes, and labeled, so that any one who likes to see them can do so.

Of the advantage which a machine which will collapse or fold up when desired, but retain its form on the road, offers in convenience, it is unnecessary for me to speak.

Of double machines, the Rucker tandem bicycle seems to me to be in every respect the best, but I should add that I speak only from imagination and not from experience. The independent steering, the impossibility of capsizing forward or sideways, the position of the rider over his work, the absence of any little wheel with its mud throwing and vibrating tendencies, combine to make a machine which ought to be superior in almost every desirable quality to any other; what it may be in practice I hope to hear in the discussion.

Of double tricycles, the Sociable has been tried by many, and is practically a failure in so far as traveling quickly and easily is concerned. The Tandem, though it presents so objectionable an appearance, seems likely to become a favorite, for it surpasses any single tricycle, and rivals the bicycle in speed. How it may compare in comfort or in safety with the single machine, perhaps those few who are well acquainted with them will say; at any rate, in the case of the Humber, greater stability is given to the steering, owing to the weight of the front rider.

Time will not allow me to say more of these machines, or to attack the subject of steam, electric, or magic tricycles, which I had hoped to do. With steam and electricity we are well acquainted; by magic tricycles, I mean those driven by a motor which, without any expense, will drive one twenty miles an hour, up or down hill, with perfect safety. Highway regulations, and certain reasons not well understood, have at present prevented these contrivances from making a revolution.

There remains one machine which must be considered separately, for it cannot be classed with any other. This is the Otto bicycle. My opinion of this machine is so pronounced that I do not care to state it fully. I shall merely give the reasons why I prefer it to anything else, and in so doing I shall be taking the first step in the discussion, in which it will be interesting to hear from riders of other machines the reasons for their preference.

In the first place, the evils of a third or little wheel, the cause of trouble in all tricycles, are avoided. There is none of the vibration which makes all other machines almost unbearable to Ottoists, vibration which tricyclists have learnt to consider a necessary accompaniment of cycling, but which has, no doubt, been diminished by the use of the spring support of the front steering Humber. It would be presumptuous in me to make any remarks on the effect of this vibration on the human system; we shall all be anxious to hear what our Chairman has to say on this point. By having only two wheels, we have only two tracks, so that we can travel at a fair speed along those places in the country called roads, which consist of alternate lines of ruts and stones, where a three-track machine could not be driven, and where, from the quantity of loose limestone in the ruts, a little wheel of a two-track tricycle would be likely to suffer. By having no little wheel, we can ride in dirty weather without having the rest of our machine pelted with mud, so that cleaning takes less time than it does with anything else. As I have already remarked, the small wheel is the culprit which makes the bicycle and tricycle drive so heavily on a soft road. The ease with which the Otto can therefore be run through the mud astonishes every one. Having no little wheel, we can obtain the full advantage of the high 56 inch wheel, which almost every one prefers. As I have ridden all combinations, from a 50 inch geared up to 60 inch, to a 60 inch geared level, I can speak from experience of the increased comfort to be derived from these large wheels, though for speed only they do not compare with the smaller and lighter wheels geared up. A further point gained by the use of two wheels only is the fact that the whole weight of machine and rider is on the driving-wheel, as it is also on the steering-wheel, so that by no possibility can the wheels be made to slip in the driving, or to fail in steering from want of pressure upon them.

The most important consequence, however, is the absence of any fixed frame. In all machines, bicycles and tricycles, with the usual fixed frame, a position is found for the saddle which is, on the whole, most suitable. For some particular gradient it will be perfect; on a steeper gradient the treadles will be further in advance, but with a steeper gradient the rider should be more over the front of the treadles. To get his weight further to the front, he has to double up in the middle, and assume a position in which he cannot possibly work to advantage. The swinging frame of the Otto carries the treadles, of necessity, further back, so that the Ottoist, when working at his hardest, is still upright, with his hands in the line between his shoulders, and his feet and his arms straight, so that he can hold himself down, and employ his strength in a perfectly natural position. On going down a slope, the fixed frame of a bicycle or tricycle leans forward, and places the rider in such a position that extra weight is thrown on his arms and his shoulders, whereas the swing frame of the Otto goes back, and the rider of necessity assumes that position in which his arms are relieved of all strain. In so far as the general position taken by the automatic Otto frame is concerned, nearly the same effect can be obtained by using the swing frame of the Devon tricycle, which can be shifted and locked in any position which the rider wishes, or by the sliding saddle, which can be slid backward or forward and locked so as to place the rider in one of three positions. Though the rider can by these devices assume nearly that position with respect to the treadles which is most advantageous, he cannot obtain that curious fore and aft oscillation made use of by the Ottoist in climbing hills, which, as the model on the table shows, enables him to get past the dead points without even moving, and which, therefore, makes the Otto by far the best hill-climbing machine there is, if account is taken of the high speeding with which all Ottoists ride. This is a proposition which none who knows the machine will question for one moment.

The freedom of motion resulting from the swing of the frame of the Otto gives a pleasurable sensation, which those who have only experienced the constrained motion of a three-wheeler cannot even understand.

The very peculiar method of driving and steering, which seems so puzzling to the novice, especially if he is a good rider of other machines–for in that case he is far worse off than one who has never ridden anything–give the rider, when he is familiar with them, a control over the machine which is still surprising to me. In the first place, the machine will run along straight, backward or forward, so long as the handles are let alone. This automatic straight running is a luxury, for until a deviation has to be made, the steering handles need not be touched, and the rider may, if sufficiently confident, travel with his arms folded or his hands in his pockets. The rigid connection between the cranks and the wheels does away with all the backlash, which is so unpleasant with chain or toothed wheel gearing. There is no differential gear or clutch, but the machine possesses the advantage of the clutch over the differential gear when meeting with unequal resistance on a straight course, for each wheel must travel at the same speed; but, in turning a corner, instead of driving the inner wheel only, which is done by the clutch or both wheels equally, which is the case with differential gear, each wheel is driven, but the outer one more than the inner. At high speeds, the steering of the Otto has this advantage, that whereas, with a given action on a tricyle, the same deviation will be effected in the same _space_ at high as at low speeds, the same action on the Otto will, at high speeds, produce the same deviation in the same _time_ as it does at low speeds; and so instead of becoming more sensitive at high speeds, as is the case with the tricyle, the steering of the Otto remains the same. This is because the steering of the tricycle depends on a kinematical, that of the Otto on a dynamical principle.

In another respect, no machine can approach the Otto; at almost any speed the rider can, if there is reason, instantly dismount, by which action he puts on the brakes, and the machine will save him from falling, stopping with him almost instantly. As is well known, we can move backward and forward, we can twist around and around in our own width, or can ride over bricks with impunity.

One objection to the machine is the difficulty of learning, which is considerable, but which presents no danger. This difficulty has been much exaggerated, for before the present powerful brake was applied it did require considerable skill to ride it down a steep hill. The way to do this must still be learnt, but it is now comparatively easy. For going down steep hills, the front steering tricycle is without a rival; I do not know what other machine will do this better than the Otto. Lastly, the foot straps, which would be a great advantage on any machine, if only they were safe, are not–though none but riders will believe it–in any way a source of danger on the Otto. Having ridden this machine for close upon 10,000 miles, I can speak with more authority on this point than can those who are not able to sit upon it for a moment.

The only disadvantage which the machine presents is the fact that it is impossible to remove the feet from the pedals while running, without dismounting; but though they must at all times follow the pedals, the Ottoist is not, as is generally thought, working when descending a hill.

The enthusiastic terms in which every one who has mastered the peculiarities of the Otto speaks of it would be considered as evidence in its favor, if we were not all considered by other cyclists to be in various stages of lunacy.

* * * * *

THE CANAL IRON WORKS, LONDON.

Some interest is awakened in engineering circles in London, just now, by the approaching close of the old engineering works so well known as the “Canal Ironworks,” at the entrance to the Isle of Dogs, London, E. This notable establishment stands second in priority in London–that of Messrs. Maudslay, Sons & Field being the oldest–for the manufacture of marine engines. It was founded by the late Messrs. Seawards, above sixty years ago. Here was originated Seaward’s hoisting “sheers” with the traveling back leg, a modern example of which, 100 feet high, in iron, stands on the wharf. An interesting tool, also, is the large vertical boring machine for largest size cylinders; Seaward spent L5,000 upon this, and it is certainly an admirable tool. There is also the large vertical slotting machine, with a stroke up to 5 feet 2 inches, a wonderfully powerful and compact machine. The extensive collection of screwing tackle is, perhaps, unsurpassed, and extends up to 8 inches diameter. There is a peculiar erecting shop roof, which will still repay examination.

* * * * *

MARINONI’S ROTARY PRINTING PRESS.

The greatest progress that has been made in recent years in the art of printing is in the invention of the high speed press provided with continuous paper.

Three French constructors, Messrs. Marinoni, Alauzet, and Derriey, have brought this kind of apparatus to such a degree of perfection that the majority of foreign journals having a large circulation buy their presses in France. We reproduce in Fig. 1 a perspective view of the Marinoni press, and in Fig. 2 a diagram showing the parts of the same. In order to give a complete description of it, we cannot do better than to reproduce the very interesting study that has been made of it by Mr. Monet, a civil engineer.

[Illustration: FIG. 1.–MARINONI’S ROTARY PRINTING PRESS.]

The roller, J (Fig. 2), is placed in the machine in the state in which it is received from the paper manufactory. The paper unwinds, runs over the rollers, e and e’, which serve only for tautening it, and then passes between the two cylinders, A and B. The cylinder, A, carries the form, and B carries the blanket, and the paper thus receives its first impression. It afterward passes between the cylinders, A’ and B’, and receives an impression on the other side, the cylinder, A’, carrying the form, and B’ the blanket. Being now printed on both sides, it passes between the cylinders, KK’, which cut it off and allow the sheet to slide between the cords of the rollers. These latter lead the sheets over the rollers, g h, on which they wind, one over the other, when the rollers, a a’, are in the position shown by unbroken lines in the cut.

The part of the machine that holds the rollers, g h, and the different cords that wind over them, is the _accumulator_, and it is in this part of the press that the sheets accumulate, one over the other, to any number desired.

The size of the rollers, g h, and their distance apart are so regulated that when the sheet reaches the accumulator, it falls exactly on those that have preceded it. When the proper number of sheets is in the accumulator (4 or 5 being the number most employed for afterward facilitating the separation into packets on the receiving table), the two small rollers, a a’, advance over the rack, N, and the sheets, instead of continuing to roll over into the accumulator, fall on the rack and are deposited by it upon the receiving table, O.

[Illustration: FIG. 2.–MARINONI’S PRESS.]

The rack having fallen twenty times, and deposited five sheets each time, or one hundred in all, the table moves in such a way as to prevent the sheets subsequently deposited from getting mixed with them. When the rack has fallen twenty times, the table returns to its initial position.

The distributing rollers, D, come in contact with the inking rollers, I, once during each revolution of the printing cylinders, and are mounted on racking levers provided with regulating screws that permit of easily regulating the amount of ink taken up. The supports of the inking rollers are movable and can be made to approach or recede from the distributing rollers, so as to still further vary the amount of ink taken up by them.

The distributing rollers supply the ink to a roller, E, of large diameter, which, having a backward and forward motion, begins to distribute the ink and to transmit it to a second roller, F, of the same diameter. This latter then spreads it over a metallic cylinder, G, which is of the same diameter as the printing cylinders, and against which revolve three distributing rollers, H, that have a backward and forward motion.

Between the cylindrical inking table, G, and the type cylinder, there are situated inking cylinders, T, of large diameter, that constantly take up ink from the inking table and distribute it over the types.

The machine here described, when designed for printing large sized journals, has cylinders whose circumference corresponds to the size of paper for two widths of pages, and whose length is sufficient to allow it to receive two forms. Each cylinder, then, carries four forms, or eight in all, and prints two complete copies at each revolution.

The large sheet cut off by the cylinders, K K’, contains, then, two copies; and this sheet, on passing under the roller, f is again cut in two by a disk which separates it in a direction perpendicular to the cylinders.

To this press there may be added a mechanical folder of Mr. Marinoni’s invention, capable of folding a journal five times.–_Annales Industrielles_.

* * * * *

CHENOT’S ECONOMIC FILTER PRESS.

Mr. E. Chenot, who is occupied in the manufacture of wine from dry grapes, has been led to devise a new style of filter, which by reason of its mode of action and its construction, he calls the “Economic Filter Press.”

The apparatus, which is shown in the accompanying cut, consists of flat bags whose mouth may be at the top, as usual, or at the side. Through this orifice there is introduced a flat piece of wood or metal, which, like the bag, has an aperture through the center. The whole is suspended from a distributing pipe that is fixed at one end to the frame and is free at the other. This pipe is slotted beneath, and the pieces of wood or metal contain, opposite the slot, a number of small apertures that put the distributer in communication with the interior of the bags. Between these latter there are placed wire cloth frames which hold them in position and facilitate the flow of the filtered liquid. The cut shows the filter provided with a portion of its bags and frames. When all the frames are in place they are locked by causing the movable plate to move forward by means of two screws connected with an endless chain and actuated by a hand wheel. The pressure of this plate closes up the bags hermetically. Then, the feed cock being opened, the liquid flows into all the bags, deposits therein what it holds in suspension, and the clarified product flows to the inclined bottom of the filter and from thence to the exterior.

[Illustration: CHENOT’S ECONOMIC FILTER PRESS.]

The apparatus may be supplied either through an upper reservoir, a juice elevator, or a pump. The discharge is proportional to the square root of the pressure. When the bags are full of residuum, the feed cock is closed, the filter is unscrewed, and the bags and frames are taken out. With fresh bags and the same frames, it is possible to at once set the apparatus in operation again.

Before the filter is taken apart, the residuum may be exhausted by washing it either with water or steam, or by pressure. To effect the operation by pressure, the pieces of wood or metal are removed, the mouths are closed by making a fold in the top of the bags, and the latter are then put back into the apparatus or into an ordinary press and submitted to another squeezing.

To render the maneuvering of it easier, the apparatus has been given a horizontal position.–_Revue Industrielle_.

* * * * *

[American Engineer]

STEEL CHAINS WITHOUT WELDING.

We take the following description, together with the illustrations, of a method and machine for making steel chain without welding, from our valued contemporary, _Le Genie Civil_, of Paris:

When we regard an ordinary oval-linked chain endwise, it presents itself in the form of a metal cross, and it was this that gave the cue to M. Oury, of the Government Arsenals, to construct chain without welding. By a series of matrices and punches, etc., he contrives, with small loss of metal, to model a chain out of cross-shaped steel bar.

Steel is the better material for such usage, from its homogeneity, both as to composition and strength.

Referring to the plate below, Figs. 1 to 10 explain the successive steps from the bar to the finished chain.

Fig. 1 shows in plan and section the steel bar, whose length may be some 40 feet, and which would make a chain say 50 feet long. The shape of the bar presents no difficulties in the way of rolling.

Figs. 2 and 3 give, in side elevations of the two faces and sections, the first rough form of the links. These first begin to take the exterior shape with the rounding of the angles.

The operations following, represented by Figs. 4 and 5, is the piercing of the center of the links, which can later be furnished with a stay for such chains as require special strength. The point now is to detach the links, which is accomplished by oblique piercings, as shown in Fig. 6. In the operation represented by Fig. 7, the oval shape is imparted to the link, and the operation finishes as shown in Fig. 8.

Actually, the links are circular and separate. This separation is retarded as much as possible, for it is plain that it is easier to operate a rigid bar than a chain, above all when the operation necessitates its being pushed forward.

By means of a good system of heating, analogous to that employed on the large parts entering into ship construction, it is hoped to perform a major part of the operations, of which we have given but an idea, at a single heat.

[Illustration: MACHINE FOR MAKING CHAIN WITHOUT WELDING.]

These operations require work on both faces alternately–this presents no difficulties; but what appears to us most difficult to realize is _continuous work_, the bar passing through several machines which successively impress upon it the steps of progress toward the finished chain. If the machines are end on to each other in a direct line, there will necessarily be a fixed place for each tool; the rough cut chain must accurately reach the point where another tool is ready to continue the modeling. This appears to us practically impossible, the more so as the elongation which the bar takes at each stamp varies with its initial diameter.

What is more admissible is that with one heat and in the same machine an operation could be performed on the two faces perpendicularly. The bar could then be taken from one furnace and put in another immediately, to pass at once to another machine to again undergo the operations following. The work could then be done rapidly, submitting the bar to several heats.

A few words on the tools as they exist.

The most important principle to note, and on which the different machines employed are designed, is this: The punches or matrices acting on the chain at its different points of progress are put in motion by spiral springs worked by means of tappets or cams distributed over the circumference of a cylinder, having a rotary movement imparted to it by pulleys and belts.

The figures on our plate show with sufficient clearness the working of one of these machines. It will be seen that the bar traverses through and through the machine for stamping, and that it can be disengaged for a reheating before passing to subsequent operations.

* * * * *

The bog peat of Mexico is now being used on a considerable scale as fuel for locomotives, stationary engines, smelting purposes, smiths’ fires, and househould use. The peat is mixed with a proper proportion of bitumen, and is said not only to burn freely, and without smoke in much quantity, but to give a higher dynamic equivalent of heat than the same amount of wood.

* * * * *

THE BITTER SUBSTANCE OF HOPS.

[Footnote: _The Brewers’ Guardian_, from the _Zeit. f. d. gesammte Brauwesen_.]

By DR. H. BUNGENER.

Little that is definite is known of the substance or substances to which the hop owes its bitterness. Lermer has succeeded, it is true, in separating from hops a crystallized colorless substance, insoluble in water, an alkaline solution of which has a marked bitter flavor, and which easily changes on exposure to the air, assuming a resinous form. According to Lermer, the formula of this substance is C_{32}H_{50}O_{7}; it possesses the properties of a weak acid and forms a characteristic copper salt, which is soluble in ether. This hop bitter is, however, produced from the hop by a very roundabout process, by treatment of the extract with alkalies; it is not therefore regarded by many as present in this form in the hop, and they hold that it is only produced by the action of the alkalies. On the other hand, however, Etti, by a complicated extracting process, but without using an alkali, succeeded in producing a bitter substance from hops, which is, however, soluble in water.

Several experiments convinced me that there really existed in hops a crystallizable substance, insoluble in water, the alcoholic and alkaline solution of which had a bitter flavor, in short, which possessed all the properties of Lermer’s hop bitter acid. Petroleum ether is the best practical solvent in use for its isolation, as it does not dissolve the majority of the remaining constituents of the hop, especially the hop-resin, which they contain in considerable quantity. Still, the extraction of hop-bitter acid from hops is a troublesome and thankless job, the petroleum ether taking up certain substances which add greatly to the difficulty of purifying the crystals. On the other hand, we can readily and quickly attain our object, if we employ for our original material fresh lupuline from unsulphured hops.

The following process has furnished me the best results:

The lupuline is first freed from gross impurities (hop-seed leaves, etc.), and then covered with petroleum ether boiling at a low temperature (40 deg. to 70 deg.) in stoppered flasks. The mixture is shaken up from time to time. After twenty-four hours, by means of a Zullowsky filter immersed in the mass, and with the aid of a suction-pump, the dark brown solution is drawn off; then fresh ether is poured on to the lupuline, and it is allowed to stand for another twenty-four hours. After this process has been three times repeated, nearly everything the petroleum will dissolve has probably been extracted. The solutions are put together, and the petroleum ether distilled off _in vacuo_ at a low temperature, until there remains in the flask a dark brown sirup, which on cooling solidifies into a crystalline mass. This is pulverized and turned on to a filter composed of a large funnel, in which a smaller funnel covered with muslin is inserted. With the aid of a suction-pump, the greater portion of the thick, crude solution can be filtered through. There remains on the filter a highly colored crystalline “cake,” which should be pulverized with a small quantity of petroleum ether and again filtered. After this operation has been repeated three or four times, we obtain an almost colorless mass, consisting of hop-bitter acid, contaminated by small quantities of a fatty substance, and a substance which I could not isolate, and which I had at first great trouble in separating from the hop-bitter acid.

If we do not wish to utilize this crude substance at once, it will be necessary to melt it in the water bath and pour it into a bottle under close seal, where it will at once crystallize and solidify. If it remains exposed to the atmosphere, it will soon become sticky and turn partly into resin. Six kilos of lupuline, which included a large proportion of sand, furnished 400 grammes of crude hop-bitter acid. The first experiments in crystallization with petroleum ether gave poor results; it is difficult to produce the acid pure in large quantities by this process, as a small quantity of the above substance obstinately clings to it, and it readily assumes a non-crystallizable form. Our object is more readily attained if we crystallize it once from alcohol, for which purpose we dissolve it in a little lukewarm alcohol, then quickly cool the solution; flakes of a fatty substance will be separated, which are removed by filtration with the aid of a suction-pump. Then we throw a few small crystals of the acid into the solution, and after a short time crystallization commences. As soon as it appears to be ended, the mother solution is removed with the aid of a platinum cone, and the crystals washed with a little cold alcohol. The alcoholic mother solution, which still contains the chief part of the bitter acid, must be quickly evaporated, and the residue consigned to a flask. The acid crystallized from the alcohol is then recrystallized several times from petroleum-ether. In order to quickly dissolve the bitter substance, it should be carefully melted in a flask, and double its volume of ether gradually added; on its cooling, we obtain beautiful prismatic crystals, which attain a length of 1 cm., and become perfectly pure after four or five crystallizations. The mother solutions must be speedily evaporated if we still wish to obtain crystals; after a time they will only furnish a resinous residue.

The hop-bitter acid melts at 92 deg. to 93 deg.. It is easily soluble in alcohol, ether, benzol, chloroform, sulphide of carbon, and vinegar; to a lesser extent in cold petroleum ether, and not at all in water.

In the analysis I obtained figures which correspond best with those calculated from the formula C_{25}H_{35}O_{4}.

Obtained.
Calculated. ————————^———————– —–^—– 2. Crystal. 3. Crystal. 5. Crystal. 6. Crystal. p.c. p.c. p.c. p.c. p.c. p.c. p.c. C 75.19 74.79 74.83 74.9 75.04 75.05 75.07 H 8.77 8.97 8.90 8.85 8.87 8.83 8.80 O 16.04

If we shake up the ether solution of bitter substance with an aqueous solution of acetate of copper, the ether will assume a green color, and gradually deposits a green crystalline powder, a cupreous combination of the bitter acid. It is difficult to obtain in a pure state, as the solutions are readily subject to slight decomposition, accompanied by a small deposit of copper oxide. This combination is readily soluble in alcohol, to a lesser extent in ether, and is insoluble in water.

In the course of analysis, I obtained the following figures:

C 69.4 per cent. 69.3 per cent. H 7.95 ” 7.98 “
Cu 7.20 ” 7.18 “

If we suppose that the copper combines with two molecules of hop-bitter acid, by the decomposition of one of its atoms, H, we obtain the formula C_{50}H_{68}O_{8}Cu. This combination will contain 69.87 per cent. C, 7.91 per cent. H, and 7.33 per cent. Cu. The figures obtained do not perfectly coincide with those calculated; it is nevertheless probable that the formula is correct, and the combined substance analyzed was not perfectly true.

I have already referred to the fact that solutions of hop-bitter acid, if left standing too long, assume a yellow color, and on evaporation leave only a yellow resinous residue. This, as its reaction shows, evinces a complete analogy with the crystallized acid. The dark-colored mother solution, from which the crystalline cakes of bitter acid are obtained, contains a large proportion of this resinous compound, which can be isolated by treatment with a weak soda-lye; this substance, like the crystallized acid, is soluble in alkalies, and can be precipitated from an alkaline solution by an acid. Old hops furnish far less crystallizable acid than new hops; from some samples I have been able to obtain only a few crystals; the remainder had been transformed into the resinous modification.

If pure hop-bitter acid be pulverized and exposed to the atmosphere, it soon turns yellow and the surface assumes a resinous consistency. At the same time, a more pronounced odor of fatty acids and aldehydes is apparent. Still more rapidly will this oxidation occur if a thin layer of an alcoholic solution of the acid is allowed to evaporate in the air. On the other hand, we can allow hop-oil to stand for days without its odor being perceptibly changed; it appears to me more than probable that the peculiar smell of old hops is due far more to the oxidation of the bitter substance than to the oxidation of oil.

Hop-bitter acid appears to possess the character of an aldehyde and of a weak acid; for the present I am not in a position to state its constitution more clearly. Most of the oxidizing processes have an energetic effect on it, forming also considerable quantities of valerianic acid.

The question as to whether the hop owes chiefly to this acid and its resinous modifications the property of imparting a pronounced bitter flavor to a solution, I must for the present leave unanswered. The acid and its isomer are both insoluble in water; they are, on the other hand, very readily dissolved in hop oil; they also furnish a tolerably bitter solution, if boiled for a long time in water, probably on their account of their gradual decomposition. I will not for the present go further into the subject, as I hope soon to be in a position to give more definite information.

* * * * *

ST. PAUL’S VICARAGE, FOREST HILL, KENT.

This vicarage, for the Rev. Frank Jones, has recently been completed from the designs of Mr. E.W. Mountford, A.R.I.B.A.; of 22 Buckingham Street, Strand, W. C., and Mr. H. D. Appleton, A.R.I.B.A., of the Wool Exchange, Coleman Street, E. C., who were the joint architects. The builder was Mr. William Robinson, of Lower Tooting, S. W. The walls are of yellow stock bricks, with red brick arches, quoins, etc., the gables being hung with Kentish tiles and the roofs covered with Broseley tiles. The internal joinery is of pitch pine.

[Illustration: ST. PAUL’S VICARAGE, FOREST HILL.–VIEW FROM ROAD.]

[Illustration: ST. PAUL’S VICARAGE, FOREST HILL.–VIEW FROM GARDEN.]

The illustrations are from drawings by Mr. J. Stonier.–_The Architect_.

* * * * *

SOME ECONOMICAL PROCESSES CONNECTED WITH THE CLOTHWORKING INDUSTRY.

[Footnote: Read before the Society of Arts, London, May, 1884.]

By Dr. WILLIAM RAMSAY, Professor of Chemistry at University College, Bristol.

In this present age of scientific and technical activity, there is one branch which has, I think, been the subject of an article in the _Quarterly Journal of Science_. It is one which deserves attention. It was there termed “The Investigation of Residual Phenomena,” and I can conceive no better title to express the idea. The investigator who first explores an unknown region is content if he can in some measure delineate its grand features–its rivers, its mountain chains, its plains; if he be a geologist, he attempts no more than broadly to observe its most important rock formations; if a botanist, its more striking forms of vegetation. So with the scientific investigator. The chemist or physicist who discovers a new law seldom succeeds in doing more than testing its general accuracy by experiments; it is reserved for his successors to note the divergence between his broad and sweeping generalization and particular instances which do not quite accord with it. So it was with Boyle’s law that the volume of a gas varies in inverse ratio to the pressure to which it is exposed; so it is with the Darwinian theory, inasmuch as deterioration and degeneration play a part which was, perhaps, at first overlooked; and similar instances may be found in almost all pure sciences.

I conceive that the parallel from the technical point of view is a double one. For just as every technical process cannot be considered to be beyond improvement, there is always scope for technical investigation; but the true residual phenomena of which I would speak to-night are waste products. There is, I imagine, no manufacture in which every substance produced meets with a market. Some products are always allowed to run to waste, yet it is evident that every effort consistent with economy should be made to prevent such waste; and it has been frequently found that an attempt in this direction, though at first unsuccessful, has finally been worked into such a form as to remunerate the manufacturer.

It is my purpose to-night to bring under your notice methods by which saving can be effected in the cloth industry. I am aware that these methods have not much claim to novelty; but I also know that there are, unfortunately, few works where they are practiced.

The first of these relates to the saving and utilization of the soap used in wool scouring and milling. It is, perhaps, hardly necessary to explain that woolen goods are scoured by being run between rollers, after passing through a bath of soap, and this is continued for several hours, the cloth being repeatedly moistened with the lye, and repeatedly wrung out by the rollers. The process is analogous to ordinary washing; the soap dissolves the greasy film adhering to the fibers, and the “dirt” mechanically retained is thus loosened, and washed away. Now, in order to dissolve this greasy matter, a considerable amount of soap must be employed; and in the course of purification of the fabric, not merely what may be characterized as “dirt” is removed, but also short fibers, and various dye-stuffs with which the fabric has been dyed, many of which are partially soluble in alkaline water; moreover, it invariably happens that some dye does not combine with the fiber and mordant, thus becoming fixed, but merely incrusts the fiber; hence this portion is washed off when the retaining film of grease is removed from the fiber. The suds, therefore, after fulfilling this purpose, are no longer a pure solution of soap, but contain many foreign matters; and the problem is so to treat these suds as to recover the fat in some condition available for re-conversion into soap.

For this purpose wooden runnels are placed beneath the rollers, through which the cloth passes in the scouring machine, so as to collect the suds after they have been spent. These runnels lead to a wooden pipe or runnel, which receives the spent suds from all the scouring machines, and the whole of the waste, instead of being let off into the stream, polluting it, delivers into a tank or trough, which may also be constructed of wood, but, as it has to withstand the action of acid, is better lined with lead. This tank is necessarily proportioned in size to the number of scouring machines and the quantity of spent suds to be treated. When a sufficient quantity has collected, oil of vitriol, diluted with twice its bulk of water, is added, one workman pouring it in gradually while another stirs the contents of the tank vigorously. At short intervals, the liquid is tested by means of litmus paper, and when it shows a faint acid reaction, by turning the blue paper red, the addition of acid is stopped. The acid has then combined with the alkali of the soap, while the fatty acids formerly in combination with the alkali are liberated, and float to the surface of the liquid, carrying with them the impurities in the shape of short fibers and dye stuffs; the sand and heavier impurity, should any be present, sinks to the bottom.

After standing for some hours, the separation is complete. In order to separate the two layers, the tank is provided with an exit in the side, near the bottom, closed by a sluice or valve. This valve is opened, and the watery portion is allowed to escape into a sand filter bed.

The filter serves to retain any solid impurities which may still remain suspended in the water; but it will be found that the escaping water is nearly pure.

The dark brown fatty acid is mixed with a large amount of impurity, such as short wool fibers, burrs, sand, and dye stuffs washed from the wool. To remove water more completely, the semi-fluid mass is pumped from the tank, and delivered into hair-cloth filters; the liquid which drains from these bags finds its ways to the sand filters joining the drainage which formerly passed out from the tank through the sluice. After being turned over in the filter several times, the residue is transferred to canvas sacks. These sacks are placed in a filter press, where they are exposed to pressure while heated to a temperature sufficient to melt the fat. The solid impurities remain in the bags, while the fatty acids escape, and are received in a barrel or tank for the purpose. The fatty acids, when cold, are of a deep brown color, and of the consistency of butter. The residue is kept, and the method of treating it for the recovery of indigo will afterward be described.

The fatty acids are now ready for conversion into soap. It may here be remarked that, on distillation, they yield a nearly white fatty mass, which, when treated with soda-lye, is capable of yielding a perfectly white soap. But, for the clothworker’s purpose, this purification is unnecessary.

The conversion into soap is a very simple matter. As the fats are acids–a mixture of palmitic, oleic, and stearic acids–and not the glycerine salts of these acids, like ordinary fats, soap is made by causing them directly to unite with caustic soda. The fats are melted in a copper, by means of a steam-jacket, or coil of steam-pipe in the copper, and the soda-lye is run in until complete union has taken place. The exact point of neutralization can easily be found by taking out a small sample after stirring, and dissolving it in some methylated spirits. A few drops of alcoholic tincture of phenol-phthalein are then added, and as soon as a faint red color appears, addition of soda is stopped. This shows that the fatty acids have been over-saturated. Addition of a little more fat renders them perfectly neutral, and the soap is then ladled out into wooden moulds, lined with loose sheets of zinc.

The resulting soap is of a brown color, but is perfectly adapted for the purpose of wool-scouring. It should here be mentioned that, in practice, the soap is always made somewhat alkaline; in point of fact, it contains about 2 per cent. of free alkali. This is found to assist in scouring; I presume that the free alkali forms a soap with the oil added to the wool during spinning, and if no free alkali be present, this oil would not be so thoroughly removed.

It will be noticed that in this simple method of soap-making, there is no salting out to separate the true soap from the watery solution of glycerine, for no glycerine is present. The apparatus may be of the simplest nature, and on any required scale, proportionate to the size of the mill. It is a process which requires no specially skilled labor; in any works some hand may be told off to conduct the process as occasion requires; and as a very large proportion of the fatty matter is recovered, the soap-bill is reduced to a very small fraction of the amount which would be paid were recovery not practiced. And lastly, the streams are not polluted; the only waste is a little sulphate of soda, which can hardly be regarded as a nuisance, inasmuch as it is a not unfrequent constituent of many natural waters.

Let us now return to the solid matter from which the fatty acids have been removed by pressure. This brown, earthly-looking cake consists of vegetable impurity washed off from the cloth, of short fibers, and of various dye stuffs. It is divided into two lots: That which contains indigo, and that which contains none, or which contains too small a quantity for profitable extraction. And it may here be remarked, that it is advisable to collect the suds from cloth dyed with indigo separate from that to dye which no indigo has been employed. The residue from indigo-dyed cloth has always a more or less blue shade, and if much indigo is present, the well-known copper-color is evident. Of course, the amount of indigo must greatly vary, but it may rise to 8 or 10 per cent. of the total weight of the refuse.

To recover the indigo from this refuse, the somewhat hard cakes are broken up, placed in a tank, and allowed to steep in water. When quite disintegrated, they are transferred to another tank–a barrel may be used for small quantities–and thus this refuse is exposed to the reducing action of copperas and lime. The indigo is converted into indigo-white, and is rendered soluble, and it oxidizes on the surface, forming a layer of blue froth on the top of the liquid, while the remainder of the impurities sinks. This process of reduction may last for twenty-four hours, and is helped by frequent stirring.

The indigo scum is preserved, and placed in filter cloths, where it is thoroughly washed with water two or three times. The residue which has sunk to the bottom is removed, dried, and forms a valuable manure, owing to the amount of the nitrogen which it contains. Its value may be increased by addition of weak vitriol, which exercises a decomposing action on the nitrogenous matter, forming with it sulphate of ammonia. The original residue from the filter-press, if it does not contain indigo, may be at once put to similar use.

In large works, which dye their own goods, it is well known that the “fermentation vat” is in general use for indigo-dyeing. But this vat requires constant superintendence, and must be kept in continual action; besides, it is successful only on a comparatively large scale. And, moreover, it requires skilled labor. Small works, or works in which dyeing is only occasionally practiced, find it more convenient to use Schuetzenberger and Lalande’s process. Although this process is well known, a short description of it may not here be out of place.

The process depends on the reduction of indigo to indigo-white, or soluble indigo, by means of hyposulphite, or, as it is generally termed to avoid confusion with antichlore, rightly named thiosulphate of soda, hydrosulphite of soda. The formula of this substance is NaHSO_{2}, as distinguished from what is commonly known as hyposulphite of soda, Na_{2}S_{2}O_{3}. It is produced by the action of zinc-dust on the acid sulphite of soda. The zinc may be supposed to remove oxygen from the acid sulphite, NaHSO_{3}, giving hyposulphite, NaHS0_{2}. The reduction of the acid sulphite is best performed in a cask, which can be closed at the top, so as to avoid entrance of air. The acid sulphite of soda, at a strength of 50 or 60 Twaddell (specific gravity 1.26 to 1.3), is placed in the cask, and zinc-dust is added, with frequent stirring. The liquid is then mixed with milk of lime, and after again thoroughly stirring, the liquid is allowed to settle, and the clear is decanted into the dyeing-copper. The indigo, in the frothy state in which it is skimmed from the purifying barrels or tanks, is then added, with sufficient lime to dissolve it when it has been reduced. It is heated gently by a steam coil, to about 90 deg. Fahr., and the goods are dyed in it. The colors obtained by means of this indigo are light in shade, and the goods must be dipped several times if dark shades are required. But it is found better in practice not to attempt to dye dark shades by this process; the ordinary indigo-vat is better adapted for such work. The object of not wasting indigo is sufficiently attained by employing it for the purpose to which it is best adapted. Of course the recovered indigo may be used in the ordinary manner. I merely mention the most convenient way of disposing of it in works where only a small quantity is recovered, and which do not practice dyeing on an extensive scale.

I have now to ask you to turn to a different subject, namely, the scouring of wool, not by the usual agent, water, but by a liquid, bisulphide of carbon, made by the action of sulphur vapor on red hot coke or charcoal.

This, again, is not wholly a new process, for various attempts have been made to dissolve out the yolk, or _suint_, or greasy matter from unwashed wool, as it comes from the back of the sheep. Fusel oil has been patented for this purpose. Carbon disulphide has also been patented, but, as will afterward be shown, the old method of removing it from the wool injured the color and quality of the fiber, so as to make the application of this scouring agent a failure.

Wool in its unwashed state contains a considerable proportion of what is termed _suint_. This consists of the fatty matter exuded as perspiration from the sheep, along with, or in some form of combination with, potash derived from the grass on which the sheep feed. _Suint_ was first investigated by Vauquelin. He obtained it by evaporating, after filtration, the water in which raw fleeces had been washed. The residue is of a brown color, and has a saline, bitter taste. On addition of an acid to its solution in water, it coagulates, and a fatty matter rises to the surface. It is, in fact, a potash soap, to a great extent containing carbonate and acetate of potash, along with chloride of potassium and lime, probably in combination also with fatty acids. It is usually mixed with sand and carbonate of lime.

In 1828, M. Chevreul, who is still alive in Paris, although nearly a century old, published an analysis of merino wool. It consisted of:

Per cent.
Pure wool 31.23
Soluble _suint_ 32.74
Insoluble 8.57
Earthy matter 27.46
——
100.00

It is easily seen that _suint_ forms a very important constituent of raw wool. Its proportion varies, of course, according to the nature of the pasture on which the sheep are fed, the climate, etc. Wool from Buenos Ayres, for example, contains much less than that analyzed by M. Chevreul; its amount is only 12 per cent. of the weight of the raw wool.

This _suint_ contains always about 52 per cent. of residue when ignited. The composition of this residue is:

Per cent.
Carbonate of potash 86.78
Chloride of potassium 6.18
Sulphate of potash 2.83
Silica, alumina, etc. 4.21
——
100.00

In 1859, MM. Maumene and Rogelet patented the use of the water in which wool has been washed as a source of potash, and at present the extraction of potash from _suint_ is practiced in France on a large scale. The wool is washed in a systematic manner, in casks, with cold water, which runs out of the last cask with specific gravity 1.1. These washings are evaporated to dryness, and the residue is calcined in iron retorts, the gas evolved being used for illuminating purposes. The remaining cinder, consisting of a mixture of charcoal and carbonate of potash, is treated with water, whereby the latter is dissolved out. The residue left on evaporation of this water consists largely–almost entirely–of white carbonate of potash. At present there are works at Rheims, Elboeuf, Fourmier, and Vervier, which yield about 1,000 tons of carbonate of potash annually. Now, only 15,000 tons are made per annum by Leblanc’s process. In 1868, 62,000 tons of wool were imported into Britain from Australia alone, and from this 7,000 to 8,000 tons of carbonate of potash might have been recovered, the value of which is L260,000. Yet it was all wasted! And this estimate does not include the fats of the _suint_, which are worth an even greater sum.

Now, it is evident that there is here a profitable source of economy. So far as I am aware, no work in this country saves its washings. The water all goes to pollute the nearest river.

The use of carbon disulphide has again been introduced, and it is to be hoped with better success, for methods have been devised whereby the wool is not injured by it, but is even rendered better than when scoured by the old process of washing with carbonate of soda and water, or by soap. The process is due to Mr. Thomas J. Mullings. Briefly described, it consists in exposing the wool, placed in a hydro-extractor, to the action of bisulphide of carbon; the machine is then made to revolve, and the excess of solvent is expelled, carrying with it the fatty matters; the solvent finds its way into a tank, from which it flows into a still, heated with steam; the carbon disulphide, which boils at a very low temperature, distills over, and is again ready for use, while the residue in the still consists of _suint_ washed from the wool. To remove the last trace of carbon disulphide from the wool in the hydro-extractor, cold water is admitted, and when the wool is soaked, the machine again revolves. On expulsion of the water, the wool is ready for washing in the ordinary machines, but with cold water only instead of hot soapsuds.

The distinguishing features of Mr. Mullings’ process are, method by which loss of carbon disulphide is avoided, and the extraction of that solvent by means of cold water. The apparatus consists of a hydro-extractor or centrifugal machine of special construction, fitted with a bell-shaped cover, which can be lifted into and out of position by means of a weighted lever. The rim of this cover fits into an annular cup filled with water, which surrounds the top of the machine, forming an effective seal or joint. Upon the spindle of this machine is suspended, as in ordinary forms of the hydro-extractor, a perforated basket, and in this basket is placed the wool to be treated. The cover being closed, the carbon disulphide is admitted, and passing through the wool, the greasy matter is dissolved, and along with the solvent enters a reservoir. The machine is now set in motion, and the bulk of the solvent is drawn off. Cold water is then admitted, and the machine being again caused to rotate, the whole of the bisulphide is expelled. It is a curious fact that, although wool soaks remarkably easily with carbon disulphide, and at once becomes wet, cold water expels and replaces almost all that liquid. This operation takes about twenty minutes, and at one operation about 11/2 cwt. of raw wool may be treated. The wool is then washed in suitable washing machines of the ordinary type, but with cold water, no soap or alkali being employed. The bisulphide of carbon, mixed with water, flows into a reservoir, provided with diaphragms to prevent splashing, and consequent loss by evaporation. From its gravity it sinks, forming a layer below the water; it is then separated and recovered by distillation, and may be used in subsequent operations.

The point in which this process differs from the old and unsuccessful ones formerly tried, is in the expulsion of the carbon disulphide. It was imagined that it was necessary to expel it by means of heat or steam. Now, when wool moist with bisulphide is heated, it invariably turns yellow. No heat must, therefore, be employed. As already remarked, the solvent is expelled with cold water.

The residue, after distillation of the carbon disulphide, is a grayish colored, very viscous oily matter, still retaining a little bisulphide, as may be perceived from the smell. It has not the composition of ordinary _suint_, inasmuch as it contains no carbonate of potash, and indeed little mineral matter of any kind. A sample which I analyzed lost in drying 36.2 per cent., the loss consisting of water and carbon disulphide. It gave a residue on ignition amounting only to 1.6 per cent. of the original fatty matter, or 2.5 per cent. of the dried fat. The oil appears, from some experiments which I made, to be a mixture of a glycerine salt and a cholesterine salt of fatty acids. It distills without much decomposition, giving a brown-yellow oil, which fluoresces strongly, and has a somewhat pungent smell. The molecular weight was determined by saponification with alcoholic potash, and subsequent titration of the excess of potash employed. This was found to equal 546.3. This would correspond to a mixture of 18.7 parts of stearate, palmitate, and oleate of glycerine, with 81.3 parts of the same acids combined with cholesteryl. But this is largely conjecture. The boiling point of the oil is high, much above the range of a mercurial thermometer, so that it is difficult to gain an insight into its composition.

An objection which has been raised to this process is that the use of such an easily inflammable substance as bisulphide of carbon is attended by great risk of fire. Were the bisulphide to be exposed to free air, there might be force in this objection; but there is no reason why it should ever be removed from under a layer of water. The apparatus, to make all safe, should not be under the same roof as the mill; and no open fire need be used in the building set apart for it. It is easy to rotate the centrifugal machine by a belt from the mill, but better by a small engine attached, the power for which can be conducted by a small steam-pipe, and the distillation of the bisulphide can also be conducted without danger by the use of steam, as its boiling point is a very low one. The question may be naturally asked, “How do the wool and fabric made from the wool scoured by this process, compare with that scoured in the usual way?” To answer this question I may refer to a test made by Messrs. Isaac Holden & Co., at their works at Roubaix. A sample of wool was divided into two portions, one of which was scoured by the usual method, and the other by the turbine or Mullings’ process. Skilled workers then span each sample to as fine a thread as possible. Now the thinness to which a wool can be spun is evidence of its power of cohesion–in other words, its strength. The weight of 1,000 meters of the wool cleaned by the new process bore to that scoured by the old process the proportion of 1,015 to 1,085, showing that a considerably finer thread had been produced. And in total quantity, 67.53 kilos. of the former corresponded to 71.77 kilos. of the latter, showing a proportionately less waste. Such fine yarn had never before been obtained from similar wool. The yarn of the soap-washed wool could not be spun, for it could not withstand the strain; whereas, that scoured by the new process gave an admirable thread.

Another test to which it was subjected may be cited. It is the custom in France, before the wool is scoured, to put it through a sorting process, by which all the short lengths are weeded out. On a quantity exceeding 11,000 kilogrammes, half of which was scoured by the turbine process, and half by the ordinary process, the former in scouring lost in weight 2 per cent. less than the latter, although the short length extracted from the moiety thus treated weighed only 10 kilogrammes, while that taken from the other weighed over 150 kilogrammes. This saving, even with the unequal treatment, amounted in value to from 30 to 40 centimes per kilogramme.

In order that the importance of this application may be realized, I shall conclude with some figures:

The raw wool imported into England, in the year 1882, amounted to 1,487,169 bales, its total value being about L22,000,000. The cost of washing this wool by the old process, with carbonate of soda, amounts to about 1/2d. per lb. of the raw material. The cost for the total quantity of wool imported is at least L1,214,000. But it is customary to wash wool with soap, especially for the combing trade, and the cost is then about 1d. per lb. The cost of scouring by the new process is about L1 5s. per ton, or 0.13d. per lb. Taking the least favorable comparison, were all the imported wool (home-grown wool is here left out of the calculation, for want of sufficient returns) cleansed by the turbine process, the actual saving would be L1,214,500 _minus_ L315,700, or nearly L900,000 per annum.

It is thus seen that there is room for a very important economy in the treatment of wool. I have endeavored to show how economy may be practiced in scouring by the old process with soap, and how one dye stuff may be profitably recovered. It is to be hoped that means of extracting other dyes from the residue may soon follow. Unless the process were too costly to repay the trouble of extraction, it would be well worth practicing; for it would not merely be a solution of the problem of how to avoid waste, but would at the same time prevent the pollution of our streams, now, unfortunately, only too rarely pellucid; and were the last process to have as successful a future as I hope it may have, a very important saving of expense would result, and a large quantity of valuable fatty matter would no longer be thrown away.

* * * * *

[Illustration: SUGGESTIONS IN DECORATIVE ART.–DESIGNS FOR IRON GATES.]

* * * * *

COAL AND ITS USES.

[Footnote: From a paper lately read before the Association of Foremen Engineers.]

By JAMES PYKE.

The records from which geologists draw their information can scarcely be compared to written or printed histories. There are, however, nations of whom no written account exists, who perhaps never had any written history, but about whom we are still able to gather from other sources a vast amount of information. Their houses, their monuments, their weapons, and their tools have survived, and these tell us the kind of life, the state of civilization, and the skill of the men to whom they belonged; from the contents of their tombs we learn what manner of men they were physically; sometimes a sudden change in the appointments and belongings of the folk indicates that tribes which had for a long time inhabited a district were driven out and replaced by a new race. Thus, then, from waifs and strays we can piece together a fairly connected account of the events of a period long antecedent to any written history.

The investigations of Dr. Schliemann on the supposed site of the city of Troy furnish a good example of this method of research. He found lying, one on the top of another, traces of the existence of five successive communities of men, differing in customs and social development, and was able to establish the fact that some of the cities had been destroyed by fire, and that later on other towns had grown up over the buried remains of the earlier settlements. The lowest layers were, of course, the oldest, and the position of each layer in the pile gives its date, not in years, but with regard to the layers above and below it.

Now, from time immemorial nature has been at work building up monuments and providing tombs which tell us what were the events going on, and what kind of inhabitants the earth had long before man made his appearance on its surface. The monuments are the rocks which compose the ground under our feet, and these, like many ancient monuments of human construction, are the tombs of the creatures that lived while they were being built.

Many facts testify that the earth’s crust did not come into existence exactly as we find it now, but that its rocks have been built up by the slow action of natural agencies. These rocks constantly inclose the remains of plants and animals, and as it is evident that neither plant nor animal could have lived in the heart of a solid rock, this fact shows that the rock must in some way have gathered round the remains that are now found in it. Again, many of these remains, or fossils, belonged to animals that lived in water, the larger part, indeed, to marine creatures. This indicates that the rock was formed beneath the sea, and when we examine the way in which the constituents of the rock are arranged, we frequently find it to correspond exactly with the manner in which the sand and mud that rivers sweep down into the sea or lakes are spread out over the bottom of the water. In a pile of rocks formed in this way it is clear that the lowest is the oldest of all, and that any one stratum lying above is younger than the one beneath it. Further, the occurrence of rocks inland containing marine fossils far above the sea level shows that the sea and land have changed places. When, again, we find that the fossils of one group of rocks differ entirely from those of a group lying above them, we learn that one race of creatures died out and was supplanted by a new assemblage of animal forms.

These general remarks will, I trust, give some notion of the evidence which is available for reconstructing the history of those remote periods with which geology deals, and of the kind of reasoning which the geologist employs for interpreting the records that are submitted to him.